同/异双核金属配合物,Homo/hetero binuclear metal complexes
1)Homo/hetero binuclear metal complexes同/异双核金属配合物
英文短句/例句
1.Synthesis and Characterization of Phenolate-bridged Homo/Hetero Binuclear Metal Complexes and Their Mimic Enzymatic Activity酚氧桥联型同/异双核金属配合物的合成、表征及其模拟酶活性研究
2.Synthesis and Characterization of Binuclear Complexes and Their Catalytic Activitity Research;双核金属配合物的合成、表征及其仿生催化研究
3.Preliminary Study on Asymmetric Reactions Catalyzed by Chiral Binuclear Metallic Complex;手性双核金属配合物催化的不对称反应初探
4.Theoretical Studies on the Binuclear Homoleptic Rhodium Carbonyls双核多羰基铑金属配位化合物的理论研究
5.Effects of binuclear metal phthalocyanine compounds to Li/SOCl_2 battery双核金属酞菁配合物对Li/SOCl_2电池的影响
6.Synthesis and Characterization of New Phenolate-bridged Binuclear Complexes with Different Para-substituents and Their Biological Activity in Cleavage of DNA;含不同对位取代基的酚氧桥联型双核金属配合物的合成、表征及其与核酸作用研究
7.The Research of Binuclear Metal Compounds and Diacetyldioxime Supermolecule Complex双核金属配合物和丁二酮肟超分子化合物的研究
8.Self-assembly of One-Dimentional Coordination Polymers by Using Dinuclear Copper Complex as the Building Block Precursor;以双核金属铜配合物为结构单元的一维配位高分子的自组装
9.Novel Dinuclear Macrocyclic Polyamine Metal Complexes Linked with Dipeptide: Synthesis and Their Interaction with Plasmid DNA;新型双核大环多胺金属配合物的合成与DNA的性质研究
10.Synthesis and Characterization of New Phenolate-bridged Binuclear Complexes and Their Biological Activity in Cleavage of DNA;酚氧桥联双核金属配合物的合成、表征及其与DNA的作用研究
11.Synthesis and Characterization of the Binuclear Complexes and Their Research for Cleaving DNA;双核金属配合物的合成、表征及其与DNA的作用研究
12.Synthesis and Characterization of Water-soluble Mono-and bi-nuclear Complexes and Their Mimic Catalytic Activity Research;水溶性单/双核金属配合物的合成、表征及其模拟酶催化性能的研究
13.Structure and Catalytic Properties of Dinuclear Copper Complex Encapsulated in SAPO-5SAPO-5分子筛固载铜双核金属配合物的结构及催化性能
14.Ab Initio Study on Cu(Ⅱ)-VO(Ⅱ) Heterobinuclear Complex;Cu(Ⅱ)-VO(Ⅱ)异双核配合物的从头算研究
15.The Quantum Study of the Bimetallic Phosphido-Bridged Complex;磷桥联双金属配合物的量子化学研究
16.Synthesis and Characterization of One-Dimensional Coordination Polymers by Using Dinuclear Copper(Ι) Complex as Building Block;以双核金属铜（Ι）配合物为结构单元的一维配位高分子的合成与表征
17.Studies on the Syntheses, Structures and Magnetic Properties of Azido-Metal Complexes and Polynuclear Metal Cluster Compounds金属叠氮配合物和多核金属簇化合物的合成、结构与磁性研究
18.Syntheses, Structures and Properties of Polynuclear Metal Complexes多核金属配合物的合成、结构与性质研究
相关短句/例句
heterometallic complexes异核双金属配合物
3)RuNi heterobinuclear complexRuNi异金属双核配合物
1.The interactions of a new class of intelligentRuNi heterobinuclear complexes, which have been found to be potent inhibitors of HIV-I replication, with DNA having been studied.RuNi异金属双核配合物Ru(phen)_2(phen-cyclam-Ni)~(4+)(1)(phen=1,10-邻菲咯啉;cyclam=1,4,8,11-四氮杂环十四烷)和Ru(bpy)_2(bpy-cyclam-Ni)~(4+)”(2)(bpy=2,2 ’-联吡啶)具有多种重要的性质和功能;为了阐明它们在体外抗艾滋病病毒(HIV-1)活性方面的分子机理,我们用多种手段研究了这些化合物与DNA的相互作用。
4)heterobinuclear metal complex异双核金属配合物
5)homo-binuclear metal compounds同双核金属配合物
1.A novel bridged pyridine ligand with two coordinated atoms has been designed and developed; further reacted with a series of metal salts, and thus synthesized fifteen kinds ofhomo-binuclear metal compounds.设计合成了新型的具有两个配位点的桥联吡啶类配体,与一系列的金属盐反应,合成出了十五种同双核金属配合物,并采用元素分析、紫外光谱、红外光谱对产物进行了表征,并得到了Cu2(dippy)(ace)4(d)的单晶。
6)Heteronu clear metal complex异核金属配合物
延伸阅读
外轨配合物和内轨配合物根据L.C.鲍林的价键理论,具有八面体结构并有4个未成对电子的、顺磁性的[CoF6]3-,或有5个未成对电子的、顺磁性的[Fe(H2O)6]3+,其配位成键杂化轨道为4s4p34d2，所用d 轨道与s和p轨道是属于同一主能级的。这类具有nsnp3nd2形式的配合物(见配位化合物), 因为使用了外层的d轨道,所以叫做外轨配合物。两种配合物的杂化成键轨道分别如图所示。对于具有八面体结构且所有电子都是成对的、抗磁性的[Co(NH3) 6]3+， 或具有1个未成对电子的、 顺磁性的[Fe(CN)6]3-,其成键杂化轨道为3d24s4p3,使用了比s和p轨道低一级主能级层中的d轨道。这类具有(n-1)d2nsnp3型式的配合物,由于使用了内层的d轨道，所以叫做内轨配合物。在四配位体系中，具有四面体结构且有两个未成对电子的顺磁性的[NiCl4] 2-,其成键杂化轨道为4s4p3,属外轨配合物。而所有电子都成对的、抗磁性的[Ni(CN)4]2-，其成键杂化轨道为3d4s4p2,是平面正方形结构，属内轨配合物。两种配合物的杂化成键轨道如图所示。
