双核铜配合物,binuclear copper complex
1)binuclear copper complex双核铜配合物
1.Oxidative DNA cleavage promoted by twobinuclear copper complexes,Cu2(phen)2Cl2(μ-Cl)2 and [Cu2(Ophen)2]·2H2O,were investigated in this paper.考察了两种双核铜配合物Cu2(phen)2Cl2(μ-Cl)2和[Cu2(Ophen)2]。
英文短句/例句
1.The Self|assembly of One Dimensional Chain Complex of Bridged Binuclear Copper(II)一维链状桥联双核铜配合物的自组装
2.Oxidative DNA Cleavage Promoted by Binuclear Copper Complexes双核铜配合物对DNA的氧化切割活性
3.IR 、TG-DTG Analysis Investigation of a New Dinuclear Complex Containing Copper(II)and Taurine;牛磺酸双核铜配合物的红外及热分解机理分析
4.Studies on Selective Salicylate Electrode Based on the Schiff Base Complexse of Binuclear Cu(II) as Neutral Carrier以双核铜配合物为中性载体离子电极的研究
5.Synthesis and properties of binuclear copper(Ⅱ) compounds with dianion of chloranilic acid as bridging ligand;氯冉酸根桥联的双核铜配合物的合成和性质研究
6.Synthesis,Crystal Structure and Antibacterial Activity of Dinuclear Copper Complex [Cu(pht)_2(ba)_2]_2双核铜配合物[Cu(pht)_2(ba)_2]_2的合成、晶体结构和抑菌活性
7.Synthesis, Crystal Structure and Nuclease Activity of 1,10-Phenanthroline-Copper and Acyclic Polyamine Ditopic Ligand Binuclear Copper Complexes;邻菲咯啉铜及非环状多胺双核铜配合物的合成、结构与核酸酶活性研究
8.Synthesis,structural,magnetic characterization of a pyrophosphato-bridged copper complex焦磷酸根桥连的双核铜配合物的晶体结构及磁学性质研究
9.Synthesis and Crystal Structure of Binuclear Copper Complex of 4,6-Dimethyl-pyrimidin-2-mercaptoacetic Acid and o-Phenanthroline4,6-二甲基-2-巯基嘧啶乙酸·邻菲咯啉双核铜配合物的合成及晶体结构
10.Cu(Ⅱ)-Serine Schiff-base Complex Modified Glassy Carbon Electrode and Its Electrocatalysis on Ascorbic Acid氨基酸席夫碱双核铜配合物修饰玻碳电极对抗坏血酸的电催化作用
11.Synthesis of a novel μ-terephthalato binuclear copper(II) complexes;对苯二甲酸根桥联双核铜(Ⅱ)配合物的合成
12.A Novel Bicopper(Ⅱ) Chain Complex Containing NO_2~- as Bridging Ligand: Synthesis and Magnetism;亚硝酸根桥联双核铜(Ⅱ)配合物的合成与磁性
13.SYNTHESIS AND CHARACTERIZATION OF COPPER(Ⅱ) -EUROPIUM(Ⅲ) HETROBINUCLEAR COMPLEXES;铜(Ⅱ)-铕(Ⅲ)杂双核配合物的合成与性质研究
14.SYNTHESIS AND CRYSTAL STRUCTURES OFMONONUCLEAR,CONJUGATED MONONUCLEAR ANDBINUCLEAR COPPER(Ⅱ)-SCHIFF BASE COMPLEXES;单核、共轭单核、双核Schiff碱铜配合物的合成及晶体结构(英文)
15.An Electrochemical Study on Binuclear Big Bird Complexes of Ni( Ⅱ ) and Cu( Ⅱ )镍(Ⅱ)和铜(Ⅱ)的双核大鸟配合物的电化学研究
16.Self-assembly of One-Dimentional Coordination Polymers by Using Dinuclear Copper Complex as the Building Block Precursor;以双核金属铜配合物为结构单元的一维配位高分子的自组装
17.Structure and Catalytic Properties of Dinuclear Copper Complex Encapsulated in SAPO-5SAPO-5分子筛固载铜双核金属配合物的结构及催化性能
18.Synthesis and Characterization of One-Dimensional Coordination Polymers by Using Dinuclear Copper(Ι) Complex as Building Block;以双核金属铜（Ι）配合物为结构单元的一维配位高分子的合成与表征
相关短句/例句
binuclear copper(Ⅱ) complex双核铜配合物
1.Synthesis and crystal structure of a novel bis(phenoxo) bridged binuclear copper(Ⅱ) complex;双酚氧桥联双核铜配合物的合成与晶体结构
3)dinuclear copper(II) complex双核铜配合物
1.A dinuclear copper(II) complex [Cu2(oxheel)] was synthesized and characterized.合成和表征了一种双核铜配合物Cu2(oxheel)。
4)dinuclear copper(Ⅱ) complex双核铜配合物
1.Synthesis, crystal structure and magnetic properties of a thiocyanate bridged dinuclear copper(Ⅱ) complex: [μ-SCN Cu dien]_2(ClO_4)_2;硫氰酸根桥连双核铜配合物[μ-(SCN)Cu(dien)]_2(ClO_4)_2的合成、晶体结构和磁性研究
5)two-dinuclear copper complex双双核铜配合物
6)binuclear copper(Ⅱ) complex双核铜(Ⅱ)配合物
延伸阅读
外轨配合物和内轨配合物根据L.C.鲍林的价键理论,具有八面体结构并有4个未成对电子的、顺磁性的[CoF6]3-,或有5个未成对电子的、顺磁性的[Fe(H2O)6]3+,其配位成键杂化轨道为4s4p34d2，所用d 轨道与s和p轨道是属于同一主能级的。这类具有nsnp3nd2形式的配合物(见配位化合物), 因为使用了外层的d轨道,所以叫做外轨配合物。两种配合物的杂化成键轨道分别如图所示。对于具有八面体结构且所有电子都是成对的、抗磁性的[Co(NH3) 6]3+， 或具有1个未成对电子的、 顺磁性的[Fe(CN)6]3-,其成键杂化轨道为3d24s4p3,使用了比s和p轨道低一级主能级层中的d轨道。这类具有(n-1)d2nsnp3型式的配合物,由于使用了内层的d轨道，所以叫做内轨配合物。在四配位体系中，具有四面体结构且有两个未成对电子的顺磁性的[NiCl4] 2-,其成键杂化轨道为4s4p3,属外轨配合物。而所有电子都成对的、抗磁性的[Ni(CN)4]2-，其成键杂化轨道为3d4s4p2,是平面正方形结构，属内轨配合物。两种配合物的杂化成键轨道如图所示。
