RAFT聚合,RAFT polymerization
1)RAFT polymerizationRAFT聚合
1.The linear macro RAFT agent PS-SC(S)Ph was prepared byRAFT polymerization of S using 2-(ethoxycarbonyl)-2-propyl dithiobenzoate (ECPDB) and AIBN as RAFT agent and initiatior.在选择性溶剂中,大分子RAFT试剂PSSC(S)Ph和AIBN引发剂存在下,进行4乙烯基吡啶(4VP)和二乙烯基苯(DVB)的RAFT聚合,一步合成了稳定的平头型胶束。
pared with other living/controlled free radical polymerization methods, major advantages of theRAFT polymerization are i) very similar recipe and processes to the traditional free radical polymerization, ii) a larger variety of monomers, and iii) higher polymerization rate.相对于其它“活性”自山基聚合,RAFT聚合的主要优点是:ⅰ) 可以直接应用传统自由基聚合的配方和工艺基础;ⅱ) 适用单体范围广;ⅲ) 同时还能保证较高的聚合速率。
英文短句/例句
1.RAFT Polymerization of Methacrylates;甲基丙烯酸酯类单体的RAFT聚合
2.Reversible Addition-Fragmentation Chain Transfer Polymerization of (Methyl) Methacrylate Initiated by γ-Ray Irradiation;（甲基）丙烯酸甲酯在γ辐射下的RAFT聚合
3.Synthesis of Cyclic Trithiocarbonates and Related RAFT Polymerization;环状三硫酯的合成及其存在下的RAFT聚合
4.RAFT Mediated Living Radical Polymerization: Synthesis of Functional Block Copolymers and Application in Polymer-Functionalized Carbon;RAFT聚合合成功能化嵌段共聚物及聚合物接枝碳纳米管的研究
5.Ambient Temperature Reversible Addition-Fragmentation Transfer Radical Polymerization of n-Butyl Acrylate under Solar Radiation;太阳光活化丙烯酸正丁酯的室温RAFT聚合
6.Ambient Temperature Reversible Addition-Fragmentation Chain Transfer Radical Polymerization of Styrenic Monomers under UV-Visible Radiation;光活化苯乙烯及其衍生单体的室温RAFT聚合
7.Ambient Temperature RAFT Polymerization of Methacrylate under Visible Light Radiation;甲基丙烯酸酯的可见光活化室温RAFT聚合
8.Functionalization of Cyclodextrin via Cyclodextrin Xanthate Mediated RAFT Polymerization环糊精黄原酸酯引发的RAFT聚合用于环糊精改性
9.RAFT Polymerization of the Monomer Containing Benzotriazole and Its Application in the Synthesis of Functional Polymers;含苯并三唑基团单体的RAFT聚合及功能性聚合物的合成
10.Synthesis and Fluorescene Characterizations of 1,2,3-Triazole Containing Polymers via RAFT Polymerization;三氮唑乙烯基单体的RAFT聚合及其聚合物—稀土配合物荧光性能研究
11.Synthesis of Block Copolymers Via Reversible Addition-Fragmentation Chain Transfer (RAFT) Living Radical Polymerization;RAFT活性自由基聚合合成嵌段聚合物
12.Synthesis of Optically Actively Polymer via RAFT Polymerization and Studies of Their Performances;旋光性聚合物的RAFT法合成及性能研究
13.Study on Emulsifier-free Emulsion Polymerization of Styrene Systems with Reversible Addition-Fragmentation Chain Transfer (RAFT) Process;苯乙烯RAFT无皂乳液聚合体系的研究
14.Study on Emulsifier-free Emulsion Polymerization with Reversible Addition-Fragmentation Chain Transfer (RAFT) Process;RAFT试剂作用下的无皂乳液聚合研究
15.Controlled Radical Homopolymerization of Acrylic Acid Based on RAFT Polymerization基于RAFT过程的丙烯酸可控自由基聚合
16.RATRP/RAFT PolymerizationRATRP/RAFT活性自由基聚合现象的考察
17.Synthesis of High Molecular Weight PS Homopolymers with Low Polydispersity by RAFT PolymerizationRAFT法制备高分子量窄分布的PS聚合物
18.Grafted Polymer onto Carbon Nanotubes by Reversible Addition Fragmentation Chain-transfer Active Polymerization;用RAFT活性聚合方法在碳纳米管表面接枝聚合物
相关短句/例句
aqueous RAFT polymerization水相RAFT聚合
3)Surface RAFT polymerization表面RAFT聚合
4)Ambient temperature RAFT polymerization室温RAFT聚合
1.Ambient temperature RAFT polymerization is a facile and versatile technique, particularly in favor of the synthesis of well-defined polymers from thermo-sensitive or thermo-degradable monomers.在许多领域尤其热敏感或热降解单体的聚合等,室温RAFT聚合方法将成为方便简捷的技术。
5)in situ RAFT polymerization原位RAFT聚合
1.Temperature sensitive polymer brushes with densely grafted poly(N-isopropyl acrylamide) side chains on a random copolymer backbone were successfully synthesized by the combination of atom transfer radical polymerization (ATRP),"click chemistry" andin situ RAFT polymerization.ATRP、“click chemistry”和原位RAFT聚合相结合,成功的制备了具有温度响应性的聚异丙基丙烯酰胺(PNIPAM)聚合物刷。
6)RAFT Miniemulsion polymerizationRAFT细乳液聚合
延伸阅读
Raft分子式：分子量：CAS号：39807-15-3CAS号：1.484(20℃)熔点：131℃蒸气压：2.5E-5(25℃)毒性LD50(mg/kg)：大鼠急性经口LD50大于5000，兔急性经皮2000。对兔皮肤无刺激，对兔眼睛有轻微刺激。对鱼和水虱无毒。无致突变性、致畸性。性状：米色无味粉末。溶解情况：溶解度（克/升）：二氯甲烷500，乙酸乙酯121.6，正庚烷0.9，正辛烷3.5，甲苯77.6。用途：高效广谱稻田除草剂，对一年生禾本科、莎草科、阔叶杂草和某些多年生杂草效果显著，对恶性杂草四叶萍有良好的防效。主要用于水稻、马铃薯、向日葵、蔬菜、甜菜、果园等苗前防除阔叶杂草，如苘麻、鬼针草、藜属杂草、苍耳、圆叶锦葵、鸭舌草、蓼属杂草、梅花藻、龙葵、苦苣菜、节节菜等，禾本科杂草，加稗草、千金子、刺蒺藜草、兰马草、马唐、牛筋草、稷属杂草以及莎草科杂草等．制备或来源：以2，4-二氧苯酚为起始原料．经醚化、硝化、还原制得中间体取代的苯胺；再经酰化，最后与光气合环即得。备注：可制成水分散粒剂。类别：除草剂
